Chemical Compatibility Chart
EPA-600/2-80-076
April 1980
A METHOD FOR DETERMINING THE COMPATIBILITY OF CHEMICAL
MIXTURES
Municipal Environmental Laboratory
Office of Research and Development
U.S. Environmental Protection Agency
Cincinnati, Ohio 45268
Caution:
This Chart is intended as an indication of some
of the hazards that can be expected on mixing chemical
wastes. Because of the differing activities of the
thousands of compounds that may be encountered,
it is not possible to make any chart definitive
and all inclusive. It cannot be assumed to ensure
compatibiltiy of wastes because wastes are not sclassified
as hazardous on the chart, nor do any blanks necessarily
mean that the mixture cannot result in a hazard
occuring. Detailed instructions as to hazards involved
in handling and disposing of any given waste should
be obtained from the originator of the waste.
| No.
| Reactivity
Group Name
|
| 1
|
Acids, Mineral, Non-oxidizing
| 1
| |
|
|
|
|
|
|
|
|
|
|
Legend
| Code |
Consequences |
| H |
Heat
Generation |
| F |
Fire |
| G |
Innocuous
and non-flammable gas generation |
| GT |
Toxic
Gas formation |
| GF |
Flammable
Gas formation |
| E |
Explosion |
| P |
Violent
Polymerization |
| S |
Solubilization
of toxic substance |
| U |
May
be hazardous, but Unknown |
|
| 2
|
Acids, Mineral, Oxidizing
| |
2
|
| 3
|
Acids, Organic
| |
G
H
| 3
|
| 4
|
Alcohols and Glycols
|
H
|
H
F
|
H
P
| 4
|
| 5
|
Aldehydes
|
H
P
|
H
F
|
H
P
|
| 5
|
| 6
|
Amides
|
H
|
H
GT
|
|
|
| 6
|
| 7
|
Amines, Aliphatic and Aromatic
|
H
|
H
GT
|
H
|
|
H
|
| 7
|
| 8
|
Azo Compounds, Diazo Compounds and Hydrazines
|
H
G
|
H
GT
|
H
G
|
H
G
|
H
|
|
| 8
|
| 9
|
Carbamates
|
H
G
|
H
GT
|
|
|
|
|
|
G
H
| 9
|
| 10
|
Caustics
|
H
|
H
|
H
|
|
H
|
|
|
|
H
G
| 10
|
| 11
|
Cyanides
|
GT
GF
|
GT
GF
|
GT
GF
|
|
|
|
|
G
|
|
| 11
|
| 12
|
Dithiocarbamates
|
H,F
GF
|
H,F
GF
|
H,GT
GF
|
|
GF
GT
|
|
U
|
H
G
|
|
|
| 12
|
| 13
|
Esters
|
H
|
H
F
|
|
|
|
|
|
H
G
|
|
H
|
|
| 13
|
| 14
|
Ethers
|
H
|
H
F
|
|
|
|
|
|
|
|
|
|
|
| 14
|
| 15
|
Fluorides, Inorganic
|
GT
|
GT
|
GT
|
|
|
|
|
|
|
|
|
|
|
| 15
|
| 16
|
Hydrocarbons, Aromatic
|
|
H
F
|
|
|
|
|
|
|
|
|
|
|
|
|
| 16
|
| 17
|
Halogenated Organics
|
H
GT
|
H,F
GT
|
|
|
|
|
H
GT
|
H
G
|
|
H
GF
|
H
|
|
|
|
|
| 17
|
| 18
|
Isocyanates
|
H
G
|
H,F
GT
|
H
G
|
H
P
|
|
|
H
P
|
H
G
|
|
H,P
G
|
H
G
|
U
|
|
|
|
|
| 18
|
| 19
|
Ketones
|
H
|
H
F
|
|
|
|
|
|
H
G
|
|
H
|
H
|
|
|
|
|
|
|
| 19
|
| 20
|
Mercaptans and Other Organic Sulfides
|
GT
GF
|
H,F
GT
|
|
|
|
|
|
H
G
|
|
|
|
|
|
|
|
|
H
|
H
|
H
| 20
|
| 21
|
Metals, Alkali and Alkaline Earth, Elemental
|
H,F
GF
|
H,F
GF
|
H,F
GF
|
H,F
GF
|
H,F
GF
|
GF
H
|
GF
H
|
GF
H
|
GF
H
|
GF
H
|
GF
H
|
GF,H
GT
|
GF
H
|
|
|
|
H
E
|
GF
H
|
GF
H
|
GF
H
| 21
|
| 22
|
Metals, Other Elemental & Alloys as Powders,
Vapors, or Sponges
|
H,F
GF
|
H,F
GF
|
G
F
|
|
|
|
|
H,F
GT
|
U
|
GF
H
|
|
|
|
|
|
|
H
E
|
GF
H
|
|
H,F
GF
|
| 22
|
| 23
|
Metals, Other Elemental & Alloys as Sheets,
Rods, Drops, etc.
|
H,F
GF
|
H,F
GF
|
|
|
|
|
|
H,F
G
|
|
|
|
|
|
|
|
|
H
F
|
|
|
|
|
| 23
|
| 24
|
Metals and Metal Compounds, Toxic
|
S
|
S
|
S
|
|
|
S
|
S
|
|
|
S
|
|
|
|
|
|
|
|
|
|
|
|
|
| 24
|
| 25
|
Nitrides
|
GF
HF
|
H,F
E
|
H
GF
|
H,E
GF
|
GF
H
|
|
|
U
|
H
G
|
U
|
GF
H
|
GF
H
|
GF
H
|
|
|
|
GF
H
|
U
|
GF
H
|
GF
H
|
E
|
|
|
| 25
|
| 26
|
Nitriles
|
H,GT
GF
|
H,F
GT
|
H
|
|
|
|
|
|
|
U
|
|
|
|
|
|
|
|
|
|
|
H
P
|
|
|
S
|
GF
H
| 26
|
| 27
|
Nitro Compounds, Organic
|
|
H,F
GT
|
|
|
H
|
|
|
|
|
H
E
|
|
|
|
|
|
|
|
|
|
|
H,E
GF
|
|
|
|
H,E
GF
|
| 27
|
| 28
|
Hydrocarbons, Aliphatic, Unsaturated
|
H
|
H
F
|
|
|
H
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
H
E
|
|
|
|
|
| 28
|
| 29
|
Hydrocarbons, Aliphatic, Saturated
|
|
H
F
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
| 29
|
| 30
|
Peroxides and Hydroperoxides, Organic
|
H
G
|
H
E
|
|
H
F
|
H
G
|
|
H
GT
|
H,F
E
|
H,F
GT
|
|
H,E
GT
|
H,F
GT
|
|
|
|
|
H
E
|
H
|
E
|
H,F
GT
|
H
E
|
H
G
|
|
H
G
|
H,E
GF
|
H,P
GT
|
|
H
P
|
| 30
|
| 31
|
Phenols and Cresols
|
H
|
H
F
|
|
|
|
|
|
H
G
|
|
|
|
|
|
|
|
|
|
H
P
|
|
|
GF
H
|
|
|
|
GF
H
|
|
|
|
|
H
| 31
|
| 32
|
Organophosphates, Phosphothioates, Phosphodithioates
|
H
GT
|
H
GT
|
|
|
|
|
|
U
|
|
H
E
|
|
|
|
|
|
|
|
|
|
|
H
|
|
|
|
|
|
|
|
|
U
|
| 32
|
| 33
|
Sulfides, Inorganic
|
GT
GF
|
HF
GF
|
GT
|
|
H
|
|
|
E
|
|
|
|
|
|
|
|
|
|
H
|
|
|
|
|
|
|
|
|
|
|
|
H
GT
|
|
| 33
|
| 34
|
Epoxides
|
H
P
|
H
P
|
H
P
|
H
P
|
U
|
|
H
P
|
H
P
|
|
H
P
|
H
P
|
U
|
|
|
|
|
|
|
|
H
P
|
H
P
|
H
P
|
|
H
P
|
H
P
|
|
|
|
|
H
P
|
H
P
|
U
|
H
P
| 34
|
| 101
|
Combustible and Flammable Materials, Miscellaneous
|
H
G
|
H,F
GT
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
H,F
G
|
|
|
|
H,F
GF
|
|
|
|
|
H,F
GT
|
|
|
|
| 101
|
| 102
|
Explosives
|
H
E
|
H
E
|
H
E
|
|
|
|
|
H
E
|
|
H
E
|
|
|
H
E
|
|
|
|
|
|
|
|
H
E
|
H
E
|
H
E
|
E
|
E
|
|
|
|
|
H
E
|
H
E
|
|
H
E
|
H
E
|
H
E
| 102
|
| 103
|
Polymerizable Compounds
|
P
H
|
P
H
|
P
H
|
|
|
|
|
P
H
|
|
P
H
|
P
H
|
U
|
|
|
|
|
|
|
|
|
P
H
|
P
H
|
P
H
|
P
H
|
P
H
|
|
|
|
|
P
H
|
P
H
|
|
P
H
|
|
|
H
E
| 103
|
| 104
|
Oxidizing Agents, Strong
|
H
GT
|
|
H
GT
|
H
F
|
H
F
|
H,F
GT
|
H,F
GT
|
H
E
|
H,F
GT
|
|
H,E
GT
|
H,F
GT
|
H
F
|
H
F
|
|
H
F
|
H
GT
|
H,F
GT
|
H
F
|
H,F
GT
|
H,F
E
|
H,F
E
|
H
F
|
|
H,F
E
|
H,F
GT
|
H
E
|
H
F
|
H
F
|
H
G
|
H
F
|
H,F
GT
|
H,F
GT
|
H,F
G
|
H,F
G
|
H
E
|
H,F
GT
| 104
|
| 105
|
Reducing Agents, Strong
|
H
GF
|
H,F
GT
|
H
GF
|
H,F
GF
|
H,F
GF
|
H
GF
|
H
G
|
|
|
|
H
GT
|
H
F
|
|
|
|
H,F
E
|
H
E
|
H
GF
|
H
GF
|
H
GF
|
|
|
|
|
|
H
GF
|
H
E
|
|
|
H
E
|
H
GF
|
H,GT
GF
|
|
H
|
H
GF
|
H
E
|
H,P
GF
|
H,F
E
| 105
|
| 106
|
Water and Mixtures Containing Water
|
H
|
H
|
|
|
|
|
|
G
|
|
|
|
|
|
|
|
|
|
H
G
|
|
|
H
GF
|
H
GF
|
|
S
|
H
GF
|
|
|
|
|
|
|
|
GT
GF
|
|
|
|
|
|
GF
GT
| 106
|
| 107
|
Water Reactive Substances
| <---------EXTREMELY
REACTIVE!!!! DO NOT MIX WITH ANY CHEMICAL
OR WASTE MATERIAL!!!! EXTREMELY REACTIVE!!!!-------------->
| 107
|
|
|
| 1
| 2
| 3
| 4
| 5
| 6
| 7
| 8
| 9
| 10
| 11
| 12
| 13
| 14
| 15
| 16
| 17
| 18
| 19
| 20
| 21
| 22
| 23
| 24
| 25
| 26
| 27
| 28
| 29
| 30
| 31
| 32
| 33
| 34
| 101
| 102
| 103
| 104
| 105
| 106
| 107
|
|